External authors:

• Diana Munoz-Arango ( Pontificia Universidad Catolica de Chile , Ctr Desarrollo Urbano Sustentable CEDEUS )
• Felipe Torres -Rojas ( Pontificia Universidad Catolica de Chile )
• Natalia Tapia ( Pontificia Universidad Catolica de Chile , Ctr Desarrollo Urbano Sustentable CEDEUS )
• Marcela Vega ( Pontificia Universidad Catolica de Chile , Ctr Desarrollo Urbano Sustentable CEDEUS )
• Cristobal Alvear ( Pontificia Universidad Catolica de Chile )
• Sandra Cortes ( Pontificia Universidad Catolica de Chile , Ctr Desarrollo Urbano Sustentable CEDEUS )
• Alejandra S. Vega ( Pontificia Universidad Catolica de Chile , Ctr Desarrollo Urbano Sustentable CEDEUS )
• Raill Calderon ( Universidad Bernardo O'Higgins )
• Robert Nerenberg ( University of Notre Dame )

Abstract:

Perchlorate and chlorate are endocrine disruptors considered emerging contaminants (ECs). Both oxyanions are commonly associated with anthropogenic contamination from fertilizers, pesticides, explosives, and disinfection byproducts. However, the soils of the Atacama Desert are the most extensive natural reservoirs of perchlorate in the world, compromising drinking water sources in northern Chile. Field campaigns were carried (2014-2018) to assess the presence of these ECs in the water supply networks of twelve Chilean cities. Additionally, the occurrence of perchlorate, chlorate and other anions typically observed in drinking water matrices of the Ata-cama Desert (i.e., nitrate, chloride, sulfate) was evaluated using a Spearman correlation analysis to determine predictors for perchlorate and chlorate. High concentrations of perchlorate (up to 114.48 & mu;g L-1) and chlorate (up to 9650 & mu;g L-1) were found in three northern cities. Spatial heterogeneities were observed in the physico-chemical properties and anion concentrations of the water supply network. Spearman correlation analysis indicated that nitrate, chloride, and sulfate were not useful predictors for the presence of perchlorate and chlorate in drinking water in Chile. Hence, this study highlights the need to establish systematic monitoring, regulation, and treatment for these EC of drinking water sources in northern Chilean cities for public health protection.